• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    1. A method of recovering the gallium contained in an aqueous solution of highly alkaline sodium aluminate by exchange of chemical species between a stationary phase consisting of a microporous adsorbent resin impregnated with a 7-alkenyl 8-hydroxy quinoline charge and the aqueous phase of sodium aluminate characterised by the fact that prior to impregnation the dry resin has a specific surface area, measured by the BET method, which is at least equal to 450 sq.m/g of resin, a pore volume at least equal to 1500 cu.mm/g of resin, a mean pore diameter of between 8.0 and 50.0 nm with at least 80% of this volume consisting of pores of a diameter comprised between 4.0 and 500.0 nm, an expansion rate in an aqueous medium not exceeding 20%, and in that it is impregnated with 7-alkyl or alkenyl 8-hydroxy in a proportion of 250 to 350 g per litre of dry resin.
    公开号:SU1637665A3
    申请号:SU874203493
    申请日:1987-10-22
    公开日:1991-03-23
    发明作者:Ламеран Жан-Мишель
    申请人:Алюминиюм Пешинэ (Фирма)；
    IPC主号:
    专利说明:

    This invention relates to metallurgy, in particular, to the recovery of gallium from aluminate solutions manufactured by Bayer.
    The purpose of the invention is to increase the degree of gallium extraction directly from Bayer solutions.
    Example 2.9 l of Amberlite XAD 1180 resin dried in a cabinet at 80 ° C to constant weight. This resin is contacted with a solution of 7- (5,5,7,7-tetramethyl-1-octene-3-yl) -8-oxoquinoline (TMOOH) in alcohol, preferably in ethanol, to concentrations of 15-30 wt.%
    of this compound in ethanope. In this case, this value is 15% by weight. The amount of impregnation solution is calculated so that the ratio of extractant to the volume of dry resin is 250-350 g per liter. In this example, this value is 275 g / l0.
    This operation can be carried out in one or several successive stages with intermediate drying at 60 ° C under vacuum, which allows the removal of ethanol and control.
    00
    one
    with
    OE
    ate
     s
    To add the amount of adsorbed extractant.
    After the last drying under vacuum, the resin is impregnated with deionized water, degassed under vacuum, then loaded into a column. The pore volume of the resin used is 1500 mm3 / g dry resin, the average pore diameter is 80-500 X, with at least 80% of the pore volume formed by pores with a diameter of 40-5000 A. The degree of swelling of the resin in an aqueous medium does not exceed 20%. The mass obtained after impregnation corresponds to the fixation of almost the entire TMOOX. The volume of resin in the column is 3.2 liters with a layer height of 30 cm. 80 liters of Bayer liquid, containing 80-140 g / l of sodium hydroxide, 60-110 g / l of alumina and 150-350 mg / l of gallium, with a temperature of 40 ° C is passed through the resin at a rate of 20 l / h o The content in the gallium solution is at the beginning of the process when entering the column 240
    and 90 mg / l at the end of the process.
    After washing the resin with 6 liters of water, 4.3 n sulfuric acid solution is passed through the column at a flow rate of 20 l / h for 30 minutes.
    The maximum concentration of gallium in a solution of sulfuric acid after passing through the resin is 6.8 g / l in 3.2 l of solution. Analysis of the solutions obtained shows that the resin fixes 3.75 g of gallium per liter of resin in the column.
    Thus, the proposed method allows the extraction of gallium directly from Bayer production solutions.
    5 0 S
    five
    权利要求:
    Claims (2)
    [1]
    1. A method for extracting gallium from a highly alkaline aqueous solution of sodium aluminate, comprising contacting, at 40-60 ° C, a solution of sodium aluminate containing gallium with a microporous adsorption resin impregnated with 7-alkyl- or 7-alkenyl-8-oxyquinoline organic reagent in a diluent , and the subsequent elution of gallium with a solution of sulfuric acid, characterized in that, in order to increase the degree of gallium recovery,
    from solutions of Eyyer production, the contacting of the gallium-containing solution is carried out with a non-polar and hydrophobic polystyrene-based resin with a specific surface area of 450 mg / l, with a pair volume of at least 1500 mm3 per 1 g of resin, with an average pore diameter of 80-500 A, 80% of the pore volume is pores with a diameter of 40-5000 A with an expansion coefficient in an aqueous medium of not more than 20% by volume, using 7- (5,5,7,7-tetramethyl-1-octene) as an organic reagent during impregnation -3-yl) -8-hydroxyquinoline in the amount of 250-350 g per 1 liter of dry resin, diluted 10-30% ethanol, and gallium is extracted from Bayer solutions containing 80-140 g / l of sodium hydroxide, 60-110 g / l of alumina and 150-350 mg / l of gallium at a ratio of Bayer initial solution and resin 2-10: 1.
    [2]
    2. A method according to claim 1, characterized in that the elution is carried out at a concentration of sulfuric acid of 3-6 N. when the ratio of the volumes of solution of sulfuric acid and resin 2-10: 1.
    类似技术:
    公开号 | 公开日 | 专利标题
    SU1637665A3|1991-03-23|Method of gallium extraction from aqueous strong alkalinous solution of sodium aluminate
    US6046131A|2000-04-04|Method for the preparation of a cesium-separating sorbent
    US4046687A|1977-09-06|Process for the adsorptive removal of arsenic, antimony and/or bismuth from an aqueous solution
    EP0234319B1|1992-06-10|Method for recovering gallium
    US4631177A|1986-12-23|Method for recovering gallium
    Koshima et al.1980|Collection of mercury from artificial sea-water with activated carbon
    US4332031A|1982-05-25|Silica removal process and alumina composition used therein
    JP2000024647A|2000-01-25|Adsorbing and removing method of arsenic dissolved in water
    US4558022A|1985-12-10|Regeneration of caustic impregnated activated carbons
    US5624655A|1997-04-29|Process for purifying hydrogen peroxide aqueous solution
    US6123836A|2000-09-26|Process for the removal of acid compounds from a hydrocarbon stream
    US4559182A|1985-12-17|Method for purifying cresidine sulfonic acid by resin extraction
    KR100500730B1|2005-07-12|A method for manufacturing extraction rosin for extraction and separation of an rare earth element
    AU664563B2|1995-11-23|Process for the separation of the aqueous phase from cellulose acetate
    RU2104085C1|1998-02-10|Zeolite-based sorbent
    SU1765220A1|1992-09-30|Method of extracting metals from solutions
    CN109456162B|2021-11-26|Method for purifying chromatographically pure 4-methyl-2-pentanone
    RU2096333C1|1997-11-20|Method of separation of rhenium and molybdenum by low-base anionite of porous structure
    RU2100463C1|1997-12-27|Method for recovering vanadium from vanadium- and-silicon-containing process liquors
    Miesiąc et al.1998|Pertraction of penicillin G in hollow fiber contained liquid membranes
    Pease1966|Herbicide Method, Determination of Sulfamate Residues
    US5676838A|1997-10-14|Process for isolating hydroxymonocarboxylic and tricarboxylic acids
    EP0058116B1|1984-07-25|Improved regeneration of caustic impregnated activated carbon
    SU1279964A1|1986-12-30|Method of producing aluminium oxide
    JPS63162636A|1988-07-06|Production of absolute alcohol
    同族专利:
    公开号 | 公开日
    GR3000806T3|1991-11-15|
    YU193087A|1989-02-28|
    JPH0438453B2|1992-06-24|
    DE3762885D1|1990-06-28|
    FR2605646A1|1988-04-29|
    US5424050A|1995-06-13|
    HU200802B|1990-08-28|
    AU8007287A|1988-04-28|
    FR2605646B1|1989-04-21|
    JPS63123439A|1988-05-27|
    AU591354B2|1989-11-30|
    YU45043B|1991-06-30|
    ES2015319B3|1990-08-16|
    BR8705694A|1988-05-31|
    CN87106967A|1988-05-11|
    EP0265356B1|1990-05-23|
    IE60593B1|1994-08-10|
    EP0265356A1|1988-04-27|
    HUT45567A|1988-07-28|
    CN1010595B|1990-11-28|
    CA1332109C|1994-09-27|
    IE872850L|1988-04-24|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    FR922904A|1946-02-26|1947-06-23|Semi-automatic shotgun|
    US3637711A|1968-03-25|1972-01-25|Ashland Oil Inc|Beta-alkenyl substituted 8-hydroxyquinolines|
    IL50120A|1976-07-25|1981-03-31|Yeda Res & Dev|Process for the extraction of metal ions from solutions using polymer impregnated with extraction agent|
    GB2047564B|1978-03-27|1983-01-26|Bend Res Inc|Separator membrane and process using such membrane for removing ions from an aqueous solution|
    US4389379A|1980-08-15|1983-06-21|Societe Miniere Et Metallurgique De Penarroya|Process for selective liquid-liquid extraction of germanium|
    GB2100709B|1981-06-30|1985-03-13|N Proizv Ob Temp|Process for recovery of metals from aqueous solutions and suspensions|
    AU560201B2|1981-09-17|1987-04-02|Sumitomo Chemical Company, Limited|Gallium recovery|
    FR2532296B1|1982-08-26|1985-06-07|Rhone Poulenc Spec Chim|PROCESS FOR THE EXTRACTION OF GALLIUM USING SUBSTITUTED HYDROXYQUINOLEINS AND ORGANOPHOSPHORUS COMPOUNDS|
    JPS6316333B2|1983-08-11|1988-04-08|Mitsubishi Chem Ind|
    CH655710A5|1983-11-17|1986-05-15|Sulzer Ag|METHOD FOR LIQUID-LIQUID EXTRACTION OF GALLIUM FROM SODIUM ALUMINATE SOLUTION WITH THE AID OF AN ORGANIC EXTRACTION AGENT.|
    JPH0545526B2|1985-06-10|1993-07-09|Sumitomo Chemical Co|
    CN1012812B|1986-01-31|1991-06-12|三菱化成株式会社|Method for recovering gallium|
    JPS6352101B2|1986-03-12|1988-10-18|Kogyo Gijutsuin|
    EP0285055B1|1987-04-03|1992-06-24|Sumitomo Chemical Company, Limited|Process for recovery of gallium by chelate resin|
    FR2616157A1|1987-06-02|1988-12-09|Pechiney Aluminium|PROCESS FOR EXTRACTING AND PURIFYING GALLIUM FROM BAYER LIQUEURS|FR2616157A1|1987-06-02|1988-12-09|Pechiney Aluminium|PROCESS FOR EXTRACTING AND PURIFYING GALLIUM FROM BAYER LIQUEURS|
    DE3814916A1|1988-05-03|1989-11-16|Int Gallium Gmbh|METHOD FOR OBTAINING GALLIUM|
    FR2654439B1|1989-11-15|1992-02-07|Rhone Poulenc Chimie|METHOD FOR RECOVERING GALLIUM FROM BASIC SOLUTIONS CONTAINING THEM.|
    US6334219B1|1994-09-26|2001-12-25|Adc Telecommunications Inc.|Channel selection for a hybrid fiber coax network|
    AT197167T|1995-04-27|2000-11-15|Dow Chemical Co|EXTRUDED, OPEN-CELLED MICROCELLULAR FOAMS AND METHOD FOR THEIR PRODUCTION|
    US6128330A|1998-11-24|2000-10-03|Linex Technology, Inc.|Efficient shadow reduction antenna system for spread spectrum|
    FR2813615A1|2000-09-07|2002-03-08|Metaleurop Sa|GALLIUM EXTRACTION PROCESS|
    GB2399344A|2003-03-12|2004-09-15|Univ Loughborough|Surface-coated solvent impregnated resins|
    CN101864525A|2010-04-27|2010-10-20|中国神华能源股份有限公司|Method for extracting gallium from fly ash|
    CN102965502A|2011-09-01|2013-03-13|广西大学|Solid-phase extraction method for separating enriched gallium|
    CA2791611C|2011-10-31|2014-05-06|Dow Global Technologies Llc|Enhanced staged elution of loaded resin|
    CN102534214B|2012-01-18|2014-03-12|西安蓝晓科技新材料股份有限公司|Method for recycling gallium from Bayer mother solution by using chelate resin|
    CN104624170B|2014-12-25|2017-02-01|佛山市博新生物科技有限公司|Adsorbent for treating gram bacterial infection and blood perfusion device|
    CN109439899B|2018-12-25|2020-06-02|广东省稀有金属研究所|Method for adsorbing and separating gallium from sulfuric acid leaching solution of zinc replacement residues|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    FR8615362A|FR2605646B1|1986-10-24|1986-10-24|EXTRACTION OF GALLIUM FROM BAYER LIQUORS USING AN IMPREGNATED ADSORBENT RESIN|
    [返回顶部]